I've created a very simple MySQL scanning module for the metasploit framework.

1. Download the mysql_version file and rename it to mysql_version.rb and put it in the framework-3.2/modules/auxiliary/scanner/mysql directory of your metasploit installation.
http://compukid.no-ip.org/dev/scripts/mysql_version

2. Use using msfcli
./msfcli auxiliary/scanner/mysql/mysql_version RHOSTS=192.168.0.1 E
[*] 192.168.0.1:3306, MySQL server version: 5.0.81-1-log (Protocol 10)

3. More options:
set THREADS to 10 and RHOSTS to 192.168.0.0/24 to scan a whole network.